Isothermal Reversible Expansion





An isothermal process is a process which is conducted in a manner such that the temperature remains constant during the entire operation.

Consider an ideal gas confined in a cylinder with a frictionless piston.

Suppose it expands reversibly from volume V_1 \text{to} V_2 at a constant temperature, the pressure of the gas is successfully reduced from P_1 \text{to} P_2.

Isothermal reversible expansion

Isothermal reversible expansion


The reversibly expansion of the gas takes place in a finite number of infinitesimally small intermediate steps. To start with the external pressure, P_{gas} is arranged equal to the internal pressure of the gas P_{ext} and the piston remains stationary.

If P_{ext} is decreased by an infinitesimal amount dP the gas expands reversibly and the piston moves through a distance dl.

Since dP is so small, for all practical purposes hence, P_{ext} = P_{gas} = P

The work done by gas in one infinitesimal step (dw), can be expressed as:

dw = P \times A \times dl (A = cross-section area of piston)

P \times dV

 

where dV is the increase in volume. The total amount of work done by the isothermal reversible expansion of the ideal gas from V_1 \text{to} V_2 is, therefore,

w = \int^{_2}_{V_1}P. dV…..(vii)

By the ideal gas equation,

P = \dfrac{nRT}{V}

 

w = \int^{V_2}_{V_1} \dfrac{nRT}{V} dV

 

nRT \int^{V_2}_{V_1} \dfrac{dV}{V}

 

On integration, we get

\text{Since} P_1V_1 = P_2V_2

 

\dfrac{V_2}{V_1} = \dfrac{P_1}{P_2}

 

 w = n R t \hspace{2mm} ln \dfrac{P_1}{P_2}

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