According to Ohm’s law, the strength of current, C flowing through a conductor of resistance, R is directly proportional to the potential difference E, applied across the conductor. This statement may be represented by;
The current is measured in ampere, the potential difference in volt and the resistance in ohm. The reciprocal of resistance, R, is known as conductance or electrical conductivity and is expressed in units of reciprocal ohm(r, 0) ohms inverse mhos or Siemen (S).
Ohm’s law is also valid to electrolytic solutions. Thus the resistance R offered by an electrolyte to the passage of electricity is proportional to the length I and inversely proportional to the area of across solution, a of the column of the electrolyte lying between the electrodes.
a where p is a constant called resistivity or specific resistance, defined as the resistance offered by one of the metal. The reciprocal of specific resistance is known as specific conductivity. Thus substituting the terms conductivity and specific conductivity in place of resistance and specific resistance, in the above expression, we have
The ratio 1/a is constant for a particular conductivity cell and is known as cell constant and is denoted by x. If I 1 cm and , then
Specific conductivity = Conductivity
Thus specific conductivity may be defined as: “The conductivity of one of the solution of electrolyte is called specific conductivity”.
Equivalent conductivity may be defined as: “The conductivity of the solution containing one equivalent of the electrolyte when placed between two sufficiently large electrodes kept one cm apart”.
It is denoted by the symbol (lambda); where V is the volume in mL containing one equivalent of the solute. The equivalent conductivity is also related with specific conductivity and the volume V in mL containing one equivalent of the electrolyte, as:
Sometimes, the term, molar conductivity is used for comparison among different electrolytes. This may be defined as: “The conductivity of a solution containing one mole of the electrolyte when placed between two sufficiently large electrodes kept one cm apart”.
It is denoted by the symbol (mew) where V is the volume in mL containing one mole of the soulte. Similar to equivalent conductivity, molar conductivity is also related with specific conductivity as:
- Henderson’s Equation Henderson derived an equation to calculate the pH value of...
- Faraday’s law electrolysis Faraday’s law electrolysis Michael Faraday (1834) stated two laws on...
- Ostwald’s Dilution Law Ostwald’s dilution law is the application of the law of...
- Effect of Temperature on Rate of Reaction The rate of reaction increases with rise of temperature. It...
- Pressure Temperature Law Pressure Temperature Law (Amonton’s Law): According to this Law at...